LoKI

Broadband SANS

LoKI is a SANS instrument that will enable scientists to answer the challenging materials science questions of tomorrow in fields from health and aging, to sustainability and energy security. One of the first instrument concepts to be proposed and moved into construction, LoKI will be part of the early science programme at ESS.

Instrument Class

Large-Scale Structures

Beam Port Allocation

N7

Lead Scientist

Andrew Jackson

Lead Engineer

David Turner

LoKI instrument view

Small angle neutron scattering (SANS) is a technique that is applied across a spectrum of scientific disciplines, with users from chemistry, physics, biology, materials science, engineering and geoscience. LoKI is designed primarily with the needs of the soft matter, biophysics and materials science communities in mind and the trend in all of these fields is towards complexity and heterogeneity.

Complexity

Complexity manifests itself in the study of multi-component systems studied as a function of multiple environmental conditions (e.g. pressure, temperature, shear, magnetic field) simultaneously. In order to be able to examine the possible parameter space, a combination of faster measurements, measurements on smaller sample volumes, and measurements with good signal-to-noise is required.

Heterogeneity

Heterogeneity is seen both spatially and temporally. Spatial heterogeneity is manifested as different structure at different length scales, from the nanometre scale to the millimetre scale. This can be driven by applied stimuli such as shear, flow, electrical or magnetic fields, or by intrinsic structural features of the material. Examples of the former are shear banding in surfactant systems and the flow re-orientation of polymers. Examples of the latter are nano-composite materials, multi-component gels, and porosity in rocks. To address this spatial heterogeneity requires a wide Q range to examine the sub-micrometre length scales and small beams to examine the heterogeneity on the millimetre scale. Furthermore, since these heterogeneities are often driven by non-equilibrium conditions, the accessible Q range must be measured simultaneously. Temporal heterogeneity is seen in the form of stimulus-response experiments (e.g. shear relaxation), in the kinetics of formation of materials when the components of the material are mixed (e.g. mixed micelle formation) and in the growth of biomolecule aggregates such as fibrils. In order to examine these systems with sufficient time resolution a high neutron flux is required and a wide simultaneous Q range is needed.

Smaller Samples

Not only are the systems of interest becoming more complex and heterogeneous, but they are also becoming smaller in volume. Examples of this are the small amounts of protein complexes that can be purified and deuterated, thin film systems such as organic photovoltaics, and bio-mimetic or polymer membranes.

Not So Small Angles

The ability to reach Q values above the typical 0.8 to 1.0 Å-1 opens up significant areas of new science when combined with wide-angle scattering studies and the rapidly advancing fields of materials simulation. The study of, for example, ionic liquids and their ordering in the presence of solutes calls for the combination of SANS, wide-angle scattering and atomistic or coarse-grained molecular dynamics simulations. The analysis techniques used in biological solution scattering, such as ab-initio shape reconstruction, require data out to high Q as do studies of nano-composite materials where the size of the particles or domains may be only a few nanometres.

LoKI is the shorter of the two SANS instruments being built at ESS. The sample position is located at 23.5 m from the source and the maximum sample-to-detector distance is 10 m.

The initial chopper system consists of four choppers in two pairs with variable phasing, and operating at 14 Hz or 7 Hz (“pulse-skipping”), to control the neutron spectrum delivered to the sample. These parameters provide for a wide wavelength bandwidth of up to 20 Å when the instrument is operated at 7 Hz.

The detector system on LoKI is designed to cover a wide, and as continuous as possible, angular coverage. The initial scope provides for 0 to 45 degrees in scattering angle (theta) and 0 to 180 degrees of azimuthal angle coverage (phi).

The combination of the wide bandwidth and detector coverage gives access to the wide simultaneous Q-range required for the study of non-equilibrium and multi-scale structures.

Once ESS is operating at full power, LoKI will be the world's leading SANS instrument in terms of the combination neutron flux delivered to sample and simultaneously accessible Q-range. Simulations indicate that the neutron flux will be as high as 109 n/s/cm2, and a dynamic Q-range (Q_max/Q_min) of greater than 1000 times will be possible.

The wide science scope of LoKI requires a wide range of specialist sample environment including rheometers, shear cells, flow cells, electromagnets, rotating sample holders, automated mixing and sampling devices, ancillary measurements (UV-Vis, IR, Raman), and strain rigs.

Sample Environment Systems for Fluids Including Gases, Liquids and Complex Fluids (FLUCO)

The FLUCO platform will provide sample environment for fluids in neutron scattering experiments in soft matter and life science at ESS.

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The LoKI team at IKON13 in Lund, September 2017

ESS

  • Andrew Jackson
    Lead Scientist
    ESS
  • David Turner
    Lead Engineer
    STFC
  • Richard Heenan
    Scientist
    STFC
  • Clara Lopez
    Integration Engineer
    ESS
  • A. Jackson et al. "LoKI - A Broad Band High Flux SANS Instrument for the ESS", Proc ICANS XXI (2016) DOI:10.11484/jaea-conf-2015-002
  • Jackson, Andrew et al. (2014) "ESS Construction Proposal : LoKI - A broad-band SANS Instrument", ZENODO, DOI:10.5281/zenodo.13302