SKADI

The Small-K Advanced Diffractometer

The Small-K Advanced DIffractometer SKADI is a versatile small-angle neutron scattering (SANS) instrument, which will enable scientists to perform a wide range of investigations on topics requiring small scattering angles to access long length scales. The scientific areas targeted by SKADI include investigations of smart materials, biological and medical research, magnetic materials and materials for energy storage, as well as experiments on nanomaterials and nanocomposites or colloidal systems. These experiments promise a high potential impact on science and society. To maximize the societal applicability of these studies SKADI is designed to accommodate in-situ measurements with custom-made sample environments to provide "real-world" conditions.

Instrument Class

Large-Scale Structures

Beam Port Allocation

E3

Lead Scientist

Sebastian Jaksch

Lead Engineer

Romuald Hanslik

Like any SANS instrument SKADI is catering to a wide range of experimental needs. SANS makes length scales on the order of Angstroms up to micrometers accessible and is therefore extensively used when structural properties of the sample on the micro- and mesoscopic scale are of importance.

Additionally, SKADI offers the possibility to polarize the neutrons and therefore also gives access to the spin state of the atoms in the sample, which are of importance when magnetic phenomena are investigated. All this is combined with a large sample area (3x3 m2) in which a wide range of custom-made sample equipment can be installed.

SKADI will provide data with a high spatial and temporal resolution. SANS measurement of 9 wt% C28H57-PEO5 micelles in D2O at KWS2, MLZ. While for a wavelength resolution of 20% the primary structure peak is visible all other peaks vanish. Only using the 5% wavelength resolution the higher order peaks become visible, also the splitting of the first peak allows an improved determination of the sample structure. Today such experiments are either possible with a high time resolution (down to the ms scale) or a high spatial resolution (as shown above with 5% wavelength resolution). SKADI will provide both simultaneously so that also structure emergence during transitions can be investigated in real time.

All those capabilities gives rise to a plethora of possible experiments. In order to highlight those possibilities here a few examples are given:

In Situ Chemical Reaction

Being located at a high-flux source gives SKADI the possibility to reach down to timescales that were previously inaccessible to SANS experiments. This is supported by the high dynamic range of SKADI, allowing the experimenter to collect data over three orders of magnitude in Q, and hence also in real space, simultaneously. Also, single scattering images should be possible to obtain within approximately 100 ns. This allows to follow reaction and mixing mechanisms in real time. Such experiments can be pressure-release experiments where supercritical gases are dissolved in a liquid, which upon pressure release undergoes polymerization, or the mixing behavior and structure formation of two liquids.

Stroboscopic Investigations of Magnetic Liquids

Magnetic liquids are liquids in which magnetic nanoparticles are dispersed. Those can be investigated under rapidly changing external electromagnetic fields and the exhibit corresponding structural changes. When the external field is oscillating, the pulse of the neutron source can be synchronized to the external field and thus stroboscopic measurements of the sample evolution under magnetic fields become possible. In this mode, structural changes can be followed on the timescale of microseconds.

High-Resolution Structure Formation

Highly concentrated solutions often form superstructures (Quasi-crystals) of the dissolved particles. Today’s SANS instruments are limited in investigating these structures due to their limited wavelength resolution of maximum 5%. SKADI will push that limit down to 1% and open new possibilities for the investigation of superstructures on the mesoscale. This capability is also highly advantageous for the investigation of biological or medical samples, such as proteins which benefit from such an improved resolution.

Schematic overview of SKADI. The overall length of SKADI is approximately 55 m. From left to right neutrons are transported from the source to the sample and detector system. The bunker provides shielding against radiation. In the chopper and collimation system the resolution of the experiment is selected. Polarization of the incoming neutrons can also be selected. The large sample area accommodates custom sample environments. Finally, the detectors are housed in the detector tube.

SKADI is a 55 m long small-angle neutron scattering instrument. The first part of the instrument, the neutron beam extraction is within the bunker, which provides shielding against radiation coming from the target.

Here the neutron flight tube is bent, so there is no direct line of sight between the sample and the neutron source. Also the heavy shutter in order to shut of the neutron flux to the source is located there.

The neutron beam is conditioned in the collimation stretch right outside the bunker. Here the choppers, the polarizer and several blinds serve to constrict the transmitted neutrons to those useful for a neutron scattering experiment.

Photograph of a technical demonstrator of the SoNDe detector technology. The Li-glass on the front of the multi anode photo-multipliers is grooved in order to improve crosstalk behavior between the pixels. All modules can be read out and controlled via a network connection.

The sample area finally houses the sample itself and the sample environment, which provides the controlled conditions needed for an experiment. In order to also allow experiments with “real-world” environments a large 3x3 m2 is available, that allows the installation of versatile and custom-made sample environments that can provide nearly any conceivable condition, in terms of temperature, pressure, gas environment, rapid changing of those or intentional rupturing of a sample.

In addition to being uniquely accommodated to complex sample environments SKADI will also feature a newly developed detector system, SoNDe, which is developed within the EU Horizon2020 framework (funding reference No. 654124). This detector system will enable to use the hitherto unachieved flux of the ESS to capacity. While still being in the development stage, the current versions already outperform current detector technologies by a factor of four in terms of usable neutron flux. This detector is housed in the final detector tube.

SKADI is expected to perform at the top of its class world-wide, meaning a flux of several 108 neutrons/s/cm2 at the sample position.

The dynamic range of the covered inverse space is three orders of magnitude, that can be covered in a single shot. The total range will be 10-4 Å-1 < Q < 1 Å-1. The provided wavelength resolution can be chosen to either be variable with wavelength and then range from 5-8% or set to a constant 1%, which provides a Q-resolution of 4% or better for most of the Q-range as discussed above.

In order to allow for a reliable preparation of the sample environment as well as for a fast change between several sample environments SKADI is equipped with a common mounting system for the sample environment, that is also available for other instruments.

Here the sample environment can be prepared on a palette outside the sample area and any necessary alignment and characterization can be performed there. Then the complete setup is transferred to the sample area, where a common mounting system provides an accuracy of 100 µm for mounting the sample environment within the sample area. This allows to cut down the scheduled time for sample changes from usually around 6 h to half an hour and therefore provides correspondingly more available beam time.

Sample Environment Systems for Fluids Including Gases, Liquids and Complex Fluids (FLUCO)

The FLUCO platform will provide sample environment for fluids in neutron scattering experiments in soft matter and life science at ESS.

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Sample Environment Systems for Temperature and Fields (TEFI)

Temperatures close to absolute zero, or magnetic fields hundreds of thousands of times larger than the earth's field are often required for experiments using neutrons.

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The SKADI team at IKON13 in Lund, September 2017

ESS

  • Sebastian Jaksch
    JCNS FZJ
  • Romuald Hanslik
    ZEA-1 FZJ
  • Henrich Frielinghaus
    JCNS FZJ
  • Jacques Jestin
    LLB
  • Sylvain Désert
    LLB
  • S Jaksch, D Martin-Rodriguez, A Ostermann, J Jestin, S Duarte Pinto, WG Bouwman, J Uher, R Engels, H Frielinghaus, Concept for a time-of-flight Small Angle Neutron Scattering instrument at the European Spallation Source  NIM-A, 762, 22-30, 2014.
  • Sebastian Jaksch, Considerations about Chopper Configuration at a time-of-flight SANS Instrument at a Spallation Source NIM-A, 835, 61-65, 2016.